Synergetic active corrosion protection of AA2024-T3 by 2D- anionic and 3D-cationic nanocontainers loaded with Ce and mercaptobenzothiazole

Zadeh, M.A.; Tedim, J.; Zheludkevich, M.L.; Zwaag, S.van der; Garcia, S.J.

Journalpaper

Synergetic active corrosion protection of AA2024-T3 by 2D- anionic and 3D-cationic nanocontainers loaded with Ce and mercaptobenzothiazole

Abstract

In the current paper the corrosion inhibition synergy between Ce3+ loaded NaY-zeolite (NaY-Ce) and 2-Mercaptobenzothiazole (MBT) loaded Zn-Al layered double hydroxide (LDH-MBT) containers is presented. Solutions and water-borne epoxy coatings containing different ratios of the two loaded carriers were prepared and their protection of AA2024-T3 and damaged coatings characterized using global and local electrochemical techniques and other complementary tools. The coatings containing container-combinations showed exceptional corrosion protection over a broad range of NaY-Ce:LDH-MBT weight ratios, with 90:10 being the optimal. The current work landmarks the need for synergetic inhibiting studies devoted to carrier-inhibitor systems in coatings.

Direct Link to Publication DOI Icon

DOI Link to Publication

URL: https://publications.hereon.de/id/36820/
Authors:Zadeh, M.A., Tedim, J., Zheludkevich, M.L., Zwaag, S.van der, Garcia, S.J.
Year:2018
In: Corrosion Science
Volume:135
Pages:35 - 45
Publisher:Elsevier
Type:Journalpaper
ISSN: 0010-938X
Cite as: Zadeh, M.A.; Tedim, J.; Zheludkevich, M.L.; Zwaag, S.van der; Garcia, S.J.: Synergetic active corrosion protection of AA2024-T3 by 2D- anionic and 3D-cationic nanocontainers loaded with Ce and mercaptobenzothiazole. In: Corrosion Science. Vol. 135 (2018) 35 - 45. (DOI: /10.1016/j.corsci.2018.02.018)