KNH2–KH: a metal amide–hydride solid solution

Santoru, A.; Pistidda, C.; Soerby, M.H.; Chierotti, M.R.; Garroni, S.; Pinatel, E.; Karimi, F.; Cao, H.; Bergemann, N.; Le, T.T.; Puszkiel, J.; Gobetto, R.; Baricco, M.; Hauback, B.C.; Klassen, T.; Dornheim, M.

Journalpaper

KNH2–KH: a metal amide–hydride solid solution

Abstract

We report for the first time the formation of a metal amide–hydride solid solution. The dissolution of KH into KNH2 leads to an anionic substitution, which decreases the interaction among NH2− ions. The rotational properties of the high temperature polymorphs of KNH2 are thereby retained down to room temperature.

DOI Link to Publication

URL: https://publications.hereon.de/id/34627/
Authors:Santoru, A., Pistidda, C., Soerby, M.H., Chierotti, M.R., Garroni, S., Pinatel, E., Karimi, F., Cao, H., Bergemann, N., Le, T.T., Puszkiel, J., Gobetto, R., Baricco, M., Hauback, B.C., Klassen, T., Dornheim, M.
Year:2016
In: Chemical Communications : ChemComm
Volume:52
Issue:79
Pages:11760 - 11763
Publisher:Royal Society of Chemistry, Cambridge
Type:Journalpaper
ISSN: 1359-7345
Cite as: Santoru, A.; Pistidda, C.; Soerby, M.H.; Chierotti, M.R.; Garroni, S.; Pinatel, E.; Karimi, F.; Cao, H.; Bergemann, N.; Le, T.T.; Puszkiel, J.; Gobetto, R.; Baricco, M.; Hauback, B.C.; Klassen, T.; Dornheim, M.: KNH2–KH: a metal amide–hydride solid solution . In: Chemical Communications : ChemComm. Vol. 52 (2016) 79, 11760 - 11763. (DOI: 10.1039/c6cc05777b)