Changing the dehydrogenation pathway of LiBH4–MgH2 via nanosized lithiated TiO2

Puszkiel, J.A.; Castro Riglos, M.V.; Karimi, F.; Santoru, A.; Pistidda, C.; Klassen, T.; Bellosta von Colbe, J.M.; Dornheim, M.

Journalpaper

Changing the dehydrogenation pathway of LiBH4–MgH2 via nanosized lithiated TiO2

Abstract

Nanosized lithiated titanium oxide (LixTiO2) noticeably improves the kinetic behaviour of 2LiBH4 + MgH2. The presence of LixTiO2 reduces the time required for the first dehydrogenation by suppressing the intermediate reaction to Li2B12H12, leading to direct MgB2 formation.

DOI Link to Publication

URL: https://publications.hereon.de/id/34618/
Authors:Puszkiel, J.A., Castro Riglos, M.V., Karimi, F., Santoru, A., Pistidda, C., Klassen, T., Bellosta von Colbe, J.M., Dornheim, M.
Year:2017
In: Physical Chemistry Chemical Physics
Volume:19
Issue:11
Pages:7455 - 7460
Publisher:Royal Society of Chemistry, Cambridge
Type:Journalpaper
ISSN: 1463-9076
Cite as: Puszkiel, J.A.; Castro Riglos, M.V.; Karimi, F.; Santoru, A.; Pistidda, C.; Klassen, T.; Bellosta von Colbe, J.M.; Dornheim, M.: Changing the dehydrogenation pathway of LiBH4–MgH2 via nanosized lithiated TiO2. In: Physical Chemistry Chemical Physics. Vol. 19 (2017) 11, 7455 - 7460. (DOI: 10.1039/C6CP08278E)