Ca(BH4)2–Mg2NiH4: on the pathway to a Ca(BH4)2 system with a reversible hydrogen cycle

Bergemann, N.; Pistidda, C.; Milanese, C.; Emmler, T.; Karimi, F.; Chaudhary, A.-L.; Chierotti, M.R.; Klassen, T.; Dornheim, M.

Journalpaper

Ca(BH4)2–Mg2NiH4: on the pathway to a Ca(BH4)2 system with a reversible hydrogen cycle

Abstract

The Ca(BH4)2–Mg2NiH4 system presented here is, to the best of our knowledge, the first described Ca(BH4)2-based hydride composite that reversibly transfers boron from the Ca-based compound(s) to the reaction partner. The ternary boride MgNi2.5B2 is formed upon dehydrogenation and the formation of Ca(BH4)2 upon rehydrogenation is confirmed.

DOI Link to Publication

URL: https://publications.hereon.de/id/34617/
Authors:Bergemann, N., Pistidda, C., Milanese, C., Emmler, T., Karimi, F., Chaudhary, A.-L., Chierotti, M.R., Klassen, T., Dornheim, M.
Year:2016
In: Chemical Communications : ChemComm
Volume:52
Issue:26
Pages:4836 - 4839
Publisher:Royal Society of Chemistry, Cambridge
Type:Journalpaper
ISSN: 1359-7345
Cite as: Bergemann, N.; Pistidda, C.; Milanese, C.; Emmler, T.; Karimi, F.; Chaudhary, A.-L.; Chierotti, M.R.; Klassen, T.; Dornheim, M.: Ca(BH4)2–Mg2NiH4: on the pathway to a Ca(BH4)2 system with a reversible hydrogen cycle . In: Chemical Communications : ChemComm. Vol. 52 (2016) 26, 4836 - 4839. (DOI: 10.1039/c5cc09991a)